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The icy crust at the south pole of Enceladus exhibits large fissures that allow water from the subsurface ocean to spray into space as geysers, forming a plume of icy particles. NASA’s Cassini spacecraft, which captured this imagery in 2009, sampled those particles to reveal the chemicals contained in the ocean.

Credits: NASA/JPL-Caltech/Space Science Institute

Phosphorus, a key chemical element for many biological processes, has been found in icy grains emitted by the small moon and is likely abundant in its subsurface ocean.

Using data collected by NASA’s , an international team of scientists [including Tokyo Tech Earth-Life Science Institute researchers Yasuhito Sekine, Kento Furuya and Shuya Tan] has discovered phosphorus – an essential chemical element for life – locked inside salt-rich ice grains ejected into space from Enceladus.

The small moon is known to possess a , and water from that ocean erupts through cracks in Enceladus’ icy crust as geysers at its south pole, creating a . The plume then feeds (a faint ring outside of the ) with icy particles.

During its mission at the gas giant from 2004 to 2017, Cassini flew through the plume and E ring numerous times. Scientists found that Enceladus’ ice grains contain a rich array of minerals and organic compounds – including the – associated with life as we know it.

During a 2005 flyby, NASA’s Cassini spacecraft took high-resolution images of Enceladus that were combined into this mosaic, which shows the long fissures at the moon’s south pole that allow water from the subsurface ocean to escape into space.

Credits: NASA/JPL-Caltech/Space Science Institute

Phosphorus, the least abundant of the essential elements necessary for biological processes, hadn’t been detected until now. The element is a building block for DNA, which forms chromosomes and carries genetic information, and is present in the bones of mammals, cell membranes, and ocean-dwelling plankton. Phosphorus is also a fundamental part of energy-carrying molecules present in all life on Earth. Life wouldn’t be possible without it.

“We previously found that Enceladus’ ocean is rich in a variety of organic compounds,” said Frank Postberg, a planetary scientist at Freie Universität Berlin, Germany, who led the , published on Wednesday, June 14, in the journal Nature. “But now, this new result reveals the clear chemical signature of substantial amounts of phosphorus salts inside icy particles ejected into space by the small moon’s plume. It’s the first time this essential element has been discovered in an ocean beyond Earth.”

Previous analysis of Enceladus’ ice grains revealed concentrations of sodium, potassium, chlorine, and carbonate-containing compounds, and computer modeling suggested the subsurface ocean is of moderate – all factors that favor habitable conditions.

Seen as a bright arc in this 2006 observation by Cassini, Saturn’s E ring is fed with icy particles from Enceladus’ plume, creating wispy fingers of bright material that is backlit by the Sun. The shadowed hemisphere of the moon can be seen as a dark dot inside the ring.

Credits: NASA/JPL-Caltech/Space Science Institute

For this latest study, the authors accessed the data through NASA’s , a long-term archive of digital data products returned from the agency’s planetary missions. The archive is actively managed by planetary scientists to help ensure its usefulness and usability by the worldwide planetary science community.

The authors focused on data collected by Cassini’s instrument when it sampled icy particles from Enceladus in Saturn’s E ring. Many more ice particles were analyzed when Cassini flew through the E ring than when it went through just the plume, so the scientists were able to examine a much larger number of compositional signals there. By doing this, they discovered high concentrations of sodium phosphates – molecules of chemically bound sodium, oxygen, hydrogen, and phosphorus – inside some of those grains.

NASA’s visualization tool lets you interact with Cassini during some of its key moments flying by Enceladus. Scroll through to explore how the spacecraft discovered the moon’s subsurface ocean and its icy plume. Credit: NASA/JPL-Caltech

Co-authors in Europe and Japan then carried out laboratory experiments to show that Enceladus’ ocean has phosphorus, bound inside different water-soluble forms of phosphate, in concentrations of at least 100 times that of our planet’s oceans. Further geochemical modeling by the team demonstrated that an abundance of phosphate may also be possible in other icy in the outer solar system, particularly those that formed from primordial ice containing carbon dioxide, and where liquid water has easy access to rocks.

“High phosphate concentrations are a result of interactions between carbonate-rich liquid water and rocky minerals on Enceladus’ ocean floor and may also occur on a number of other ocean worlds,” said co-investigator Christopher Glein, a planetary scientist and geochemist at Southwest Research Institute in San Antonio, Texas. “This key ingredient could be abundant enough to potentially support life in Enceladus’ ocean; this is a stunning discovery for astrobiology.”

Although the science team is excited that Enceladus has the building blocks for life, Glein stressed that life has not been found on the moon – or anywhere else in the solar system beyond Earth: “Having the ingredients is necessary, but they may not be sufficient for an extraterrestrial environment to host life. Whether life could have originated in Enceladus’ ocean remains an open question.”

Cassini’s mission in 2017, with the spacecraft burning up in Saturn’s atmosphere, but the trove of data it collected will continue to be a rich resource for decades to come. When it was launched, Cassini’s mission was to explore Saturn, its rings, and moons. The flagship mission’s array of instruments ended up making discoveries that continue to impact far more than planetary science.

“This latest discovery of phosphorus in Enceladus’ subsurface ocean has set the stage for what the habitability potential might be for the other icy ocean worlds throughout the solar system,” said Linda Spilker, Cassini’s project scientist at NASA’s Jet Propulsion Laboratory in Southern California, who was not involved in the study. “Now that we know so many of the ingredients for life are out there, the question becomes: Is there life beyond Earth, perhaps in our own solar system? I feel that Cassini’s enduring legacy will inspire future missions that might, eventually, answer that very question.”

Source: Greicius, Tony, ed. “” NASA, June 13, 2023.