Ammonia has been in the news because of its suitability as a hydrogen carrier and fuel, in addition to being a . Existing distribution networks and the ease of turning ammonia gas into a liquid make ammonia a to transport renewable energy. For a given volume, ammonia – a molecule made up of three hydrogen atoms and one nitrogen atom – carries about 50% more hydrogen atoms than hydrogen itself.
Authors
Jamin Wood
PhD Candidate, Australian Centre for Water and Environmental Biotechnology, The University of Queensland
Bernardino Virdis
Senior Researcher, Australian Centre for Water and Environmental Biotechnology, The University of Queensland
As ammonia contains only hydrogen and nitrogen, it does not emit carbon dioxide when used. If made using green hydrogen (produced with renewable energy), its production also does not emit carbon dioxide. Therefore, could help achieve a net-zero world, particularly as a fuel for long-haul transport and heavy industry.
Australia is well placed to develop a major renewable hydrogen export industry, potentially using green ammonia. Proposed projects include , , , , and .
Unfortunately, just because ammonia doesn’t contain carbon, that doesn’t make it good for the environment. It’s a source of nitrogen pollution, which has many damaging environmental impacts. Despite Australia’s natural advantage in producing green ammonia, we ironically have the in the world.
Rarely, though, do green ammonia proponents critically assess its environmental sustainability beyond net zero claims.
Exceeding planetary boundaries
The Stockholm Resilience Centre defines that regulate Earth to support life as we know it. The boundaries of a “safe operating space” have been defined for each process.
You probably won’t be surprised to know climate change is one of the boundaries we have exceeded. You could be forgiven for thinking it has been our biggest impact on the planet. But that “honour” goes to biogeochemical flows of nutrients, mostly as a result of nitrogen fertilisers.
Why? Well it comes back to ammonia.
Unbalancing the nitrogen cycle
Nitrogen makes up as dinitrogen gas (N₂). However, in this form it is inaccessible to living organisms.
To support life, nitrogen must be converted into reactive forms such as ammonia. Once it reaches ecosystems, ammonia undergoes a series of chemical transformations. Eventually it breaks up again into N₂, and the cycle can start over again.
For millions of years, the processes in each step of the cycle have been in balance. However, industrial fertiliser production in the 20th century has thrown this cycle out of balance.
On the upside, ammonia has been a miracle chemical for growing food. An estimated 3.5 billion people are being fed thanks to chemical . This means almost half of the world’s population would go hungry if not for synthetic ammonia.
The downside is too much reactive nitrogen is ending up in the environment – more than .
In the case of excess nitrogen, crossing its planetary boundary has already had huge consequences. It has led to deterioration of ecosystems, photochemical smog, , algal blooms leading to fish kills such as the recent , , and .
Producing additional ammonia as a renewable energy carrier could make these problems even worse.
A problem of leakage
Some estimate ammonia supply chains leak it into the environment at rates as high as . However, research is limited. More widely understood natural gas supply chains may provide a ballpark figure of around .
Replacing fossil fuels with ammonia for long-haul trucks and shipping might reduce the carbon footprint of transport (which accounts for of total carbon dioxide emissions). Yet, if 2.6% of ammonia leaked from the supply chain, we this could triple the reactive nitrogen flux, further overshooting the planetary boundary. At a 6% leakage rate, it could be four times.
We all know how climate change has been changing our world – and that is at “only” 1.2 times the carbon planetary boundary. Using green ammonia as a renewable energy carrier could have an even greater impact on the nitrogen planetary boundary.
A complement to ammonia
Another renewable energy carrier can be made from green hydrogen: methanol. It’s a molecule of four hydrogen atoms and single carbon and oxygen atoms.
Like ammonia, methanol can be used as a . It could replace used in industrial processes and manufacturing. shows methanol could also enable biotechnology to better integrate with industrial processes.
More significantly, methanol doesn’t affect the nitrogen cycle. As long as it is made using a renewable source of carbon, such as carbon dioxide from , there is a net zero impact on the environment. International Energy Agency show the United States has a greater emphasis on green methanol, while Australia and Europe are more focused on green ammonia.
Environmental sustainability means more than net zero. In the case of green ammonia, holistic thinking is needed so we don’t solve one problem only to make another worse.
Jamin Wood receives funding from The Warwick and Nancy Olsen Scholarship and Research Training Program.
Bernardino Virdis receives funding from the Australian Research Council.
